Effect of Cooperative Redox Property and Oxygen Vacancies on Bifunctional OER and HER Activities of Solvothermally Synthesized CeO 2 /CuO Composites.

Herein, we report the synthesis of the CeO 2 /CuO composite as a bifunctional oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) electrocatalyst in a basic medium. The electrocatalyst with an optimum 1:1 CeO 2 /CuO shows low OER and HER overpotentials of 410 and 245 mV, respectively. The Tafel slopes of 60.2 and 108.4 mV/dec are measured for OER and HER, respectively. More importantly, the 1:1 CeO 2 /CuO composite electrocatalyst requires only a 1.61 V cell voltage to split water to achieve 10 mA/cm 2 in a two-electrode cell. The role of oxygen vacancies and the cooperative redox activity at the interface of the CeO 2 and CuO phases is explained in the light of Raman and XPS studies, which play the determining factor for the enhanced bifunctional activity of the 1:1 CeO 2 /CuO composite. This work provides guidance for the optimization and design of a low-cost alternative electrocatalyst to replace the expensive noble-metal-based electrocatalyst for overall water splitting.