Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes.
Laura M WickhamRoshan K DhunganaRamesh GiriPublished in: ACS omega (2022)
Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.
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