Phosphorus-Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry.
Johannes D R AscherlChristian NeißAlexander VogelJürgen GrafFrank RomingerThomas OeserFrank HampelAndreas GörlingMilan KivalaPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2020)
A concise synthetic route towards a new family of phosphorus-containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X-ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the development of organophosphorus functional materials with tailored properties upon further functionalization.
Keyphrases
- polycyclic aromatic hydrocarbons
- sewage sludge
- density functional theory
- molecular docking
- molecular dynamics
- air pollution
- high resolution
- ms ms
- molecular dynamics simulations
- liquid chromatography tandem mass spectrometry
- high performance liquid chromatography
- smoking cessation
- simultaneous determination
- gas chromatography mass spectrometry
- heavy metals
- magnetic resonance imaging
- ionic liquid
- computed tomography
- mass spectrometry
- monte carlo
- risk assessment
- drug discovery
- dual energy
- case control
- data analysis
- aqueous solution