Unleashing the Power of 2D MoS 2 : In Situ TEM Study of Its Potential as Diffusion Barriers in Ru Interconnects.

This study presents the utilization of MoS 2 as a diffusion barrier for metal interconnects, in situ transmission electron microscopy (TEM) observations are employed for comprehensive understanding. The diffusion-blocking ability of MoS 2 is discussed by the diffusion and phase transformation between Ru and Si via TEM diffraction and imaging. When the sample is heated to a high temperature such that MoS 2 loses the ability to block the diffusion, Si diffuses through the MoS 2 into the Ru layer, leading to the formation of Ru 2 Si 3 . Both multilayer and monolayer (1L) MoS 2 exhibit exceptional diffusion-blocking ability up to 800 °C. Furthermore, plasma-treated 1L-MoS 2 shows a slightly low diffusion-blocking temperature of 750 °C, while the dangling bonds in MoS 2 improve the interfacial adhesion. These findings suggest that MoS 2 holds great potential as a diffusion barrier for metal interconnects.