Flexible bio-memristive devices based on chicken egg albumen:Au@SiO2 core-shell nanoparticle nanocomposites.

Flexible bio-memristive (FBM) devices utilizing chicken egg albumen (CEA):Au@SiO2 core-shell nanoparticle nanocomposites were fabricated on indium-tin-oxide (ITO) coated polyethylene naphthalate (PEN) substrates. Current-voltage (I-V) curves for the Al/CEA:Au@SiO2 core-shell nanoparticle/ITO/PEN devices showed clockwise current hysteresis behaviors due to the existence of the CEA:Au@SiO2 core-shell nanoparticle nanocomposites. The endurance number of the ON/OFF switching for the FBM devices was above 102 cycles. An ON/OFF current ratio of 1 × 105 was maintained for retention times longer than 1 × 104 s. The memory characteristics of the FBM devices after bending were similar to those before bending. The memory margin and the stability of FBM devices were enhanced due to the embedded Au@SiO2 core-shell nanoparticles. The switching mechanisms occurring in the Al/CEA:Au@SiO2 core-shell nanoparticle/ITO-coated PEN devices are described on the basis of the I-V results and the filament mechanisms.