Spin-Crossover Phenomenon in Microcrystals and Nanoparticles of a [Fe(2-mpz)2Ni(CN)4] Two-Dimensional Hofmann-Type Polymer: A Detailed Nano-Topographic Study.

Christina D PolyzouOndřej MalinaJiří Tuček Radek ZborilNikos PanagiotouAnastasios J TasiopoulosNikos BoukosJohn PartheniosAlexandros N KalarakisVassilis Tangoulis

Published in: Inorganic chemistry (2019)

The diamagnetic two-dimensional Hofmann-type metal-organic framework [ZnII(2-mpz)2Ni(CN)4] has been successfully synthesized along with its isostructural hysteretic spin-crossover FeII analogue in the form of both bulk microcrystalline powder and nanoparticles. Detailed atomic force microscopy topographic study revealed a nanogrowth relationship between the height and length of the nanoparticle.

Keyphrases

metal organic framework
atomic force microscopy
body mass index
open label
room temperature
lymph node metastasis
density functional theory
transition metal
high resolution
physical activity
molecular dynamics