The unique role of pore wall nanostructurization in the intrachannel photo-ATRP for fine-tuning PMMA tacticity.
Paulina MaksymRoksana BernatKajetan KoperwasMarcin WojtyniakJulita PiechaBarbara HachułaMonika Geppert-RybczyńskaAgnieszka BrzózkaGrzegorz Dariusz SulkaMagdalena TarnackaMarian PaluchKamil KamińskiPublished in: Chemical communications (Cambridge, England) (2022)
In this paper, efficient MMA photo O -ATRP protocols conducted inside nanoreactors varying in nanostructured interfaces are reported for the first time. We showed that the microstructure of recovered polymers could be easily tuned just by implementing a given type of nanochannel ( d = 10, 19-28, 35, 160 nm).