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The crystal structure of (E)-2-ethyl-N-(4-nitro-benzyl-idene)aniline: three-dimensional supra-molecular assembly mediated by C-H⋯O hydrogen bonds and nitro⋯π(arene) inter-actions.

Marisiddaiah GirishaBelakavadi K SagarHemmige S YathirajanRavindranath Singh RathoreChristopher Glidewell
Published in: Acta crystallographica. Section E, Crystallographic communications (2018)
In the mol-ecule of the title compound, C15H14N2O2, the 2-ethyl-phenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C-H⋯O hydrogen bonds and nitro⋯π(arene) inter-actions links the mol-ecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.
Keyphrases
  • high resolution
  • ionic liquid
  • water soluble
  • single molecule