Electronic interaction between dimethyl carbonate and Li + studied by attenuated total reflectance far-ultraviolet spectroscopy.

Hitomi SatoNami UenoIchiro Tanabe

Published in: Chemical communications (Cambridge, England) (2024)

Organic electrolytes with Li + were analyzed by far-ultraviolet (≤200 nm) spectroscopy, achieved by an attenuated total reflectance setup. The spectra showed a redshift with Li + addition, attributed to the charge transfer, as revealed by quantum chemical calculations. Multivariate analysis successfully decomposed the spectra into pure solvent and Li-coordinated solvent components.

Keyphrases

ion batteries
solid state
density functional theory
ionic liquid
molecular dynamics
high resolution
single molecule
light emitting
monte carlo
solar cells