A copper(I) thiocyanate-based photoresponsive semiconducting 2D coordination polymer.
Tomoki NishiyamaHirotaka Kitoh-NishiokaSenku TanakaMasahiko MaekawaTakayoshi Kuroda-SowaMasaki YoshidaMasako KatoTakashi OkuboPublished in: Dalton transactions (Cambridge, England : 2003) (2024)
A coordination polymer, [Cu(SCN)(iqi)] n (iqi = isoquinoline), containing copper(I) thiocyanate and a nitrogen-containing π-conjugated ligand, iqi, has been synthesized and its physical properties were evaluated. This coordination polymer has a two-dimensional (2D) sheet structure consisting of copper(I) thiocyanate and shows photoluminescence derived from 3 MLCT and photoconductive properties.