Regulable cross-coupling of alcohols and benzothiazoles via a noble-metal-free photocatalyst under visible light.

Here, we realize a regulable cross-coupling reaction using alcohols as alkylating reagents to functionalize benzothiazoles. Two types of cross-coupling products are obtained with the highest isolated yields of up to 99% and 90% for alkyl- and acetyl-derived benzothiazoles, respectively, which opens up a broad research prospect for expanding alcohols as alkylating reagents.