Enhancement of Gaseous o -Xylene Elimination by Chlorosulfonic Acid-Modified H-Zeolite Socony Mobil-5.

It is important to develop effective strategies for enhancing the removal capacity of aromatic volatile organic compounds (VOCs) by modifying conventional porous adsorbents. In this study, a novel HZSM-5 zeolite-supported sulfonic acid (ZSM-OSO 3 H) was prepared through ClSO 3 H modification in dichloromethane and employed for the elimination of gaseous o -xylene. The ClSO 3 H modification enables the bonding of -OSO 3 H groups onto the HZSM-5 support, achieving a loading of 8.25 mmol·g -1 and leading to a degradation in both crystallinity and textural structure. Within an active temperature range of 110-145 °C, ZSM-OSO 3 H can efficiently remove o -xylene through a novel reactive adsorption mechanism, exhibiting a removal rate exceeding 98% and reaching a maximum breakthrough adsorption capacity of 264.7 mg. The adsorbed o -xylene derivative is identified as 3,4-dimethylbenzenesulfonic acid. ZSM-OSO 3 H demonstrates superior adsorption performance for o -xylene along with excellent recyclability. These findings suggest that ClSO 3 H sulfonation offers a promising approach for modifying various types of zeolites to enhance both the elimination and resource conversion of aromatic VOCs.