Highly Stable 3D Supercuboids to 2D ZnSe Nanosheets: Formation for a High-Efficiency Catalysis System.

Assembling into desired and higher-ordered superstructures makes nanocrystals superior candidates in a wide range of applications. Herein, we report a facile but robust colloidal chemistry method to obtain three-dimensional (3D) supercuboids from two-dimensional (2D) ZnSe nanosheets. It is well-defined that the formation mechanism of the supercuboids is based on the interaction among ligands on the ZnSe nanosheets. The highly stable supercuboids are composed of nanosheets with thickness of approximately ∼1.4 nm, and the spacing between two nanosheets in the supercuboid is revealed as ∼1.2 nm. Importantly, 2D nanosheets are readily regained by an exfoliation process of 3D supercuboids in a high-temperature solvothermal process. Furthermore, the Au@ZnSe heteronanosheets could be obtained by Au nanoparticles (NPs) decorated on 2D nanosheets. As a proof-of-concept application, the ZnSe nanosheets are applied in the catalysis of the aldol condensation reaction, which shows the high isolated yield of chalcone up to 80%.