Ionic conductivity of melt-frozen LiBH 4 films.

J TrückEfi Hadjixenophontos Yug JoshiG RichterP StenderG Schmitz

Published in: RSC advances (2019)

The fast Li conductivity of LiBH 4 envisages its use in all-solid-state batteries. Powders are commonly applied. But here, we study the formation of dense micrometer films by melting, spinning and subsequent solidifying. Characterized by electron microscopy, and spectroscopy (EDX/XPS/impedance), a reversible phase transformation is confirmed as well as a maximum conductivity of 10 3 S cm -1 .

Keyphrases

solid state
electron microscopy
room temperature
high resolution
magnetic resonance imaging
mass spectrometry
single molecule