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Building a cobaloxime-based metal-organic framework for photocatalytic aerobic oxidation of arylboronic acids to phenols.

Yonghong XiaoCan-Ming ZhuRong-Bin LiangYong-Liang HuangChun-Hua HaiJian-Rui ChenMian LiJian-Ji ZhongXiao-Chun Huang
Published in: Chemical communications (Cambridge, England) (2023)
Herein, the design and synthesis of an unprecedented cobaloxime-based zirconium metal-organic framework (Zr-TCPCo) with an she net is reported. This heterogeneous material as a photocatalyst exhibits excellent catalytic activity for aerobic oxidation of arylboronic acids to phenols. Recycling experiments demonstrate the stability and reusability of Zr-TCPCo as a robust catalyst.
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