Robust and Sustainable Indium Anode Leading to Efficient and Stable Organic Solar Cells.

The fast degradation of the charge-extraction interface at indium tin oxide (ITO) poses a significant obstacle to achieving long-term stability for organic solar cells (OSCs). Herein, w e developed a sustainable approach for recycling non-sustainable indium to construct efficient and stable OSCs and scale-up modules. It is revealed that the recovered indium chloride (InCl 3 ) from indium oxide waste can be applied as an effective hole-selective interfacial layer for the ITO electrode (noted as InCl 3 -ITO anode) through simple aqueous fabrication, facilitating not only energy level alignment to photoactive blends, but also mitigating parasitic absorption and charge recombination losses of the corresponding OSCs. As results, OSCs and modules consisting of InCl 3 -ITO anodes have achieved remarkable power conversion efficiencies (PCEs) of 18.92% and 15.20% (active area of 18.73 cm 2 ), respectively. More importantly, the InCl 3 -ITO anode can significantly extend the thermal stability of derived OSCs, with an extrapolated T 80 lifetime of approximately 10,000 hours. This article is protected by copyright. All rights reserved.