NanoTafla Nanocomposite as a Novel Low-Cost and Eco-Friendly Sorbent for Strontium and Europium Ions.
Elsayed M Abu ElgoudMohamed I AlyMostafa M HamedAbdEIAziz A NaylPublished in: ACS omega (2022)
Now the wide use of nanooxides is attributed to their remarkable collection of properties. Nanocomposites have an impressive variety of important applications. A thermal decomposition approach provides a more optimistic method for nanocrystal synthesis due to the low cost, high efficiency, and expectations for large-scale production. Therefore, in this study a new eco-friendly nanooxide composite with sorption characteristics for europium (Eu(III)) and strontium (Sr(II)) was synthesized by a one-step thermal treatment process using earth-abundant tafla clay as a starting material to prepare a modified tafla (M-Taf) nanocomposite. The synthesized nancomposite was characterized by different techniques before and after sorption processes. Different factors that affected the sorption behavior of Eu(III) and Sr(II) in aqueous media by the M-Taf nanocomposite were studied. The results obtained illustrated that the kinetics of sorption of Eu(III) and Sr(II) by the M-Taf nanocomposite are obeyed according to the pseudo-second order and controlled by a Langmuir isotherm model with maximum sorption capacities ( Q max ) of 25.5 and 23.36 mg/g for Eu(III) and Sr(II), respectively. Also, this novel low-cost and eco-friendly sorbent has promising properties and can be used to separate and retain some radionuclides in different applications.
Keyphrases
- low cost
- reduced graphene oxide
- solid phase extraction
- quantum dots
- high efficiency
- sewage sludge
- carbon nanotubes
- aqueous solution
- organic matter
- visible light
- molecularly imprinted
- gold nanoparticles
- ionic liquid
- liquid chromatography
- simultaneous determination
- tandem mass spectrometry
- mass spectrometry
- replacement therapy
- high resolution