Electrocatalytic Oxygen Reduction Reaction of Peripheral Functionalized Cobalt Porphyrins(2.1.2.1).
Yuting DongXiaojuan LvYingjie SunQian ZhaoHaitao LeiFan WuTao ZhangZhaoli XueRui CaoFengxian QiuSonglin XuePublished in: Inorganic chemistry (2024)
Two peripheral functionalized clamp-shaped cobalt porphyrin(2.1.2.1) complexes were synthesized, and their electrocatalytic ORR abilities were investigated. The crystal data and optical and redox properties of them were revised by peripheral modification. The ORR capacities and DFT calculations of F 5 PhCo and F 5 NCo suggest superior selectivity for the 4e - ORR pathway. This work further confirms the clamp-shaped cobalt porphyrin complexes are ideal Co-N 4 ORR catalysts.
Keyphrases
- metal organic framework
- reduced graphene oxide
- chemotherapy induced
- density functional theory
- quantum dots
- photodynamic therapy
- gold nanoparticles
- electron transfer
- molecular dynamics
- high resolution
- electronic health record
- high speed
- atomic force microscopy
- carbon nanotubes
- big data
- artificial intelligence
- highly efficient
- deep learning
- liquid chromatography
- monte carlo