Direct synthesis of dilithium tetraphenylporphyrin: facile reaction of a free-base porphyrin with vapor-deposited lithium.
Maik SchönigerStefan R KachelJan HerritschPhilipp SchröderMark HutterJ Michael GottfriedPublished in: Chemical communications (Cambridge, England) (2019)
A solvent-free dilithium porphyrin was synthesized by direct reaction of free-base meso-tetraphenylporphyrin with elemental lithium in ultra-high vacuum. The reaction product dilithium tetraphenylporphyrin was studied by temperature-programmed desorption mass spectrometry (TPD-MS) and hard X-ray photoelectron spectroscopy (HAXPES). The solid-state reaction is thermodynamically favored, according to density functional theory (DFT) calculations.
Keyphrases
- solid state
- density functional theory
- mass spectrometry
- high resolution
- molecular dynamics
- electron transfer
- photodynamic therapy
- multiple sclerosis
- metal organic framework
- liquid chromatography
- quantum dots
- magnetic resonance imaging
- magnetic resonance
- molecular dynamics simulations
- molecular docking
- high performance liquid chromatography
- energy transfer