Facile Synthesis of MPS3/C (M = Ni and Sn) Hybrid Materials and Their Application in Lithium-Ion Batteries.
Xianyu LiuTayyaba NajamGhulam YasinMohan KumarMiao WangPublished in: ACS omega (2021)
Herein, we successfully synthesized two novel metal thiophosphites (MTPs) hybridized with carbon, that is, NiPS3/C and SnPS3/C composites, via an environment-friendly and cost-effective approach without harsh reaction conditions. Subsequently, the electrochemical performances of NiPS3/C and SnPS3/C composites have been investigated in coin-cells, and it is revealed that MTPs/C have a significantly higher Li-storage capacity and better stability compared to the MTPs without carbon. Moreover, the SnPS3/C electrode shows a lower internal resistance and a better rate performance compared to NiPS3/C. We employed extensive ex situ experiments to characterize the materials and interpreted the remarkably improved performance of MTPs/C.
Keyphrases
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- gold nanoparticles
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- ionic liquid
- solid state
- visible light
- aqueous solution
- atomic force microscopy
- mass spectrometry
- endoplasmic reticulum stress
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- ion batteries
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