Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand.

Nicolas LeconteJules MoutetKhrystyna HerasymchukRyan M ClarkeChristian PhilouzeDominique LuneauTim StorrFabrice Thomas

Published in: Chemical communications (Cambridge, England) (2018)

The electron-rich pincer ligand 1 has been synthesized and chelated to manganese. The octahedral Mn(iv) bis(diiminosemiquinonate) and Mn(v) (diiminobenzoquinone) (diiminosemiquinonate) radicals were structurally characterized.

Keyphrases

room temperature
transition metal
metal organic framework
ionic liquid
escherichia coli
pseudomonas aeruginosa
staphylococcus aureus
solar cells