Characterizing Hygroscopic Materials via Droplet Evaporation.

Hygroscopic materials are widely used as desiccants for applications including food production, packaging, anti-icing, and gas storage. Current techniques for quantifying the hygroscopicity of materials, such as the use of a tandem differential mobility analyzer or a gravimetric vapor sorption analyzer, require complex and expensive setups. Here, we show that the hygroscopicity of any bulk material can be simply characterized by suspending it above a deposited droplet and measuring the droplet's evaporation rate. By controlling the temperature of the droplet to correspond to the dew point, we ensured that any evaporation was directly correlated with diffusive transport into the low-pressure hygroscopic material. Using Fick's law, the effective water vapor concentration of each material was extracted and nondimensionalized by the saturation concentration to obtain a hygroscopic index. This nondimensional index ranges from 0 (no hygroscopicity) to 1 (null vapor pressure) and can also be conceptualized as 1 - aw, where aw is the material's water activity.