Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl).

Wen-Ming WanAndrew W BaggettFei ChengHuina LinAshley N LammShih-Yuan LiuFrieder Jäkle

Published in: Chemical communications (Cambridge, England) (2019)

Free radical polymerization of B-vinyl- and B-styryl-functionalized azaborinine monomers gives well-defined hybrid polymers that were fully characterized by multinuclear NMR and GPC analysis; their solubility, thermal characteristics, and photophysical properties are dramatically different from those of the all-carbon polystyrene analogues.

Keyphrases

magnetic resonance
quantum dots
solid state
mass spectrometry
molecular dynamics simulations