Enhanced Second-Harmonic-Generation Response in a KH 2 PO 4 -Type Calcium Nitrate Carboxylate with Unusual Three-Dimensional Inorganic and Organic Connections.

Shuxian GuoXuehua DongLindong LuanHongmei ZengGuo-Hong Zou Zhi'en Lin

Published in: Inorganic chemistry (2022)

An organic carboxylate ligand was employed in the synthesis of a nonhygroscopic nitrate-based nonlinear-optical (NLO) material. The hybrid-framework solid has unusual three-dimensional inorganic and organic connections with high thermal stability. Sharing similar structural features with the well-known NLO material KH 2 PO 4 (KDP), this compound shows an enhanced second-harmonic-generation (SHG) response of about 1.6 times that of KDP. Theoretical calculations were carried out to reveal the origin of its SHG response.

Keyphrases

water soluble
nitric oxide
high resolution
gene expression
healthcare
molecular dynamics
genome wide
density functional theory
single cell
molecular dynamics simulations
dna methylation
mass spectrometry
health information