TEMPO-Oxidized Nanofibrillated Cellulose Assisted Exfoliation of MoS 2 /Graphene Composites for Flexible Paper-Anodes.
Shaomei CaoPanpan LiuMiao MiaoJianhui FangXin FengPublished in: Chemistry, an Asian journal (2022)
TEMPO-oxidized nanofibrillated cellulose (ONFC) with charged carboxyl groups is introduced for the efficient exfoliation of two-dimensional (2D) MoS 2 /graphene composites. As an effective dispersant agent, ONFC can be easily absorbed between the adjacent layers, so as to prevent the accumulation of the exfoliated nanosheets. With the assistance of charged ONFC, the exfoliated MoS 2 /graphene is gradually increased in the aqueous dispersions with the elongated sonication time. After dewatering, self-standing MoS 2 /Graphene/ONFC/CNTs composite films are rationally constructed using ONFC as flexible fibrous skeleton, and CNTs/graphene as 1D/2D interpenetrating electrical networks. Ultrathin MoS 2 nanosheets anchored on the 1D/2D heterogeneous networks is directly acted as an ideal paper-anode for lithium-ion batteries (LIBs) without using traditional metallic current collector. The self-standing flexible electrode materials based on natural cellulose will promote the future green electronics with high flexibility, miniaturization, and increased portability.
Keyphrases
- room temperature
- reduced graphene oxide
- ionic liquid
- quantum dots
- visible light
- carbon nanotubes
- gold nanoparticles
- transition metal
- walled carbon nanotubes
- aqueous solution
- solid state
- wastewater treatment
- low density lipoprotein
- risk assessment
- metal organic framework
- sewage sludge
- heavy metals
- anaerobic digestion