Spark plasma sintered catalytic nickel-copper alloy and carbon nanotube electrodes for the hydrogen evolution reaction.

We report the proof-of-concept of spark plasma sintered (SPS) consolidated mesoporous composite catalytic electrodes based on nickel-copper alloys and carbon nanotubes for the electrocatalytic hydrogen evolution reaction (HER) in alkaline media. The optimized electrode (203 m 2 g -1 , 5 wt% Ni 75 Cu 25 ) operated at -0.1 A cm -2 (current of -0.15 A) for 24 h with a stable overpotential of about 0.3 V. This newly described freestanding SPS approach allows the rational control of specific surface area, metal loading, and electrocatalytic performance, thus opening a new route to catalytic electrodes with controllable physical and catalytic properties.