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Total Synthesis of Endolides A and B.

Langlang LiuYian GuoQingchao LiuRanjala RatnayakeHendrik LueschTao Ye
Published in: Synlett : accounts and rapid communications in synthetic organic chemistry (2019)
The total synthesis of endolides A and B has been achieved in a concise, highly stereoselective fashion (12 steps, 16.2% and 16.0% overall yields, respectively). Key features of the route include a modified Negishi coupling between 3-bromofuran and an organozinc reagent derived from an iodoalanine derivative for the synthesis of 3-(3-furyl)-alanine derivative, and a judicious choice of reaction conditions to surmount the conformational constraints placed by converting a linear peptide into the corresponding macrocycle.
Keyphrases
  • molecular dynamics
  • water soluble
  • molecular dynamics simulations
  • single molecule
  • room temperature
  • electron transfer
  • neural network