Synthesis, Photophysics, and Langmuir Films of Polyfluorene/Permodified Cyclodextrin Polyrotaxanes.

In the present study, we investigated the effect of permodified 2,3,6-tri-O-trimethylsilyl β- and γ-cyclodextrin (TMS·β-CD, TMS·γ-CD) encapsulation on the optical, electrochemical, morphological, and supramolecular arrangements of a poly[2,7'-(9,9-dioctylfluorene-alt-2',7-fluorene)] PF copolymer. For this purpose, the photophysical properties and Langmuir monolayer formation of PF·TMS·β-CD and PF·TMS·γ-CD polyrotaxanes were investigated and compared with those of the reference PF. Surface pressure-area isotherms and Brewster angle microscopy studies indicated the capability of both polyrotaxanes to organize into larger and homogeneous 2D supramolecular assemblies at the air-water interface. The obtained results suggest that the presence of the surrounding TMS·β-CD and TMS·γ-CD macrocycles on the PF backbones leads to changes in the conformation and hydrophobicity of the film surfaces. Our investigation offers a method to assess the impact of TMS-CD encapsulation on the control of 2D monolayer formation, with particular attention on the generation of stable PF monolayers for organic electronic devices.