In situ synthesis of MWCNT-graft-polyimides: thermal stability, mechanical property and thermal conductivity.
Chunbo WangBing CongJunyu ZhaoXiaogang ZhaoDaming WangHongwei ZhouChunhai ChenPublished in: RSC advances (2020)
Herein, MWCNT-graft-polyimides (MWCNT- g -PIs) were prepared by the in situ grafting method. Strengthening the interfacial interaction between MWCNTs and polyimide chains decreased their interfacial thermal resistance ( R C ). In contrast to the R C of 10% MWCNT/PIs, the R C of 10% MWCNT- g -PI decreased by 16.7%. Hence, MWCNT- g -PIs possessed higher thermal conductivity than MWCNT/polyimides (MWCNT/PIs). Meanwhile, the T g values of all the samples (MWCNT/PIs and MWCNT- g -PIs) were greater than 399 °C (by DMA). Compared with MWCNT/PIs, 5% and 10% MWCNT- g -PIs showed enhancement in thermal stability in air. The storage modulus retentions were greater than 63% at 200 °C and 45% at 300 °C. Also, 5% and 10% MWCNT- g -PIs maintained the high tensile strength of pure PI, and the tensile modulus increased up to 2.59 GPa on increasing the loading amount of MWCNTs. This study sheds light on improving the thermal conductivity of polyimides effectively at relatively low loadings.