Effect of Long-Term Thermal Relaxation of Epoxy Binder on Thermoelasticity of Fiberglass Plastics: Multiscale Modeling and Experiments.

The work is devoted to the prediction and experimental research of the elastic bending modulus of glass-reinforced plastics with an epoxy matrix on anhydride hardener reinforced with different glass fabrics. Experimental studies have been carried out to assess the effect of thermal relaxation of the polymer matrix structure due to long-term exposure to elevated temperatures (above the glass transition temperature of the polymer matrix) on the GRP elastic bending modulus at temperatures ranging from 25 to 180 °C. It has been shown that due to the thermal relaxation of the polymer matrix structure, the GRP modulus increases significantly at temperatures above 110 °C and decreases slightly at lower temperatures. Using a multiscale simulation based on a combination of the finite-element homogenization method in the Material Designer module of the ANSYS software package and three-point bending simulation in the ANSYS APDL module, the elastic modulus of FRP was predicted concerning the temperature, its averaged structural properties, and thermal relaxation of the polymer matrix structure. We have also carried out the prediction of the temperature dependences of the modulus of elasticity of glass-reinforced plastics on different types of glass fabrics in the range from 25 to 200 °C by using the entropic approach and the layered model.