Development of Cyclic Tetrasiloxane Polymer as a High-Performance Dielectric and Hydrophobic Layer for Electrowetting Displays.

Cyclic tetrasiloxane polymer (CTP) has recently garnered interest as a hydrophobic material with unique properties. This study aims to enhance the dielectric constant of CTP films by introducing excess Si-H groups and to explore the impact of synthesis and processing conditions on the resulting properties. The film demonstrates high hydrophobicity, with contact angles of 107° in air and 165° in n -decane, along with a notable dielectric constant of 5.1°. Furthermore, the CTP film displays reversible electrowetting behavior with low contact angle hysteresis (2°) and possesses good transparency (∼99%) and thermal stability. As such, the CTP film has significant potential as a material for the electric wetting of hydrophobic dielectric layers and may serve as a promising alternative in electrowetting applications.