Oxidative Azo-Ene Cyclization.

Nolwenn DerrienJames S SharleyAleksandr E RubtsovAndrei V Malkov

Published in: Organic letters (2016)

An expedient procedure for catalytic oxidative azo-ene cyclization of allylic and homoallylic 1,2-hydrazinedicarboxylates is reported. The reaction produced a wide range of cyclic carbamate derivatives featuring an appended alkene fragment ready for further functionalization.

Keyphrases

minimally invasive
electron transfer