Birefringence-Induced Modulation of Optical Activity in Chiral Plasmonic Helical Arrays.

Chiral nanomaterials are characterized by handedness morphology on the nanoscale, manifested as preferential interaction with circularly polarized light. However, the origin of this light-matter interaction remains elusive. Here we simulated a model of chiral helical arrays of plasmonic nanoparticles with central anisotropic nanopillars to examine the effect of birefringence on the collective chiroptical response. Contrary to typical assumptions in previous works, we varied the biaxial refractive indices of the central nanopillars and observed a significant modulation of optical activity by calculating and characterizing circular dichroism (CD) spectra. The chiroptical response exhibited a sign change compared with that of the isotropic condition in a specific parametric range of negative birefringence. In addition, the CD peak increased by 3 to 16 as the ordinary refractive index increased from 1.5 to 3.0. These results are likely to be useful for designing chiral nanomaterials for applications in metamaterials, biosensors, and optoelectrical devices.