Construction of the Skeleton of Lucidumone.
Shiqiang MaZhen LiPengfei YuHongliang ShiHesi YangJiuzhou YiZheng ZhangXiaoguang DuanXingang XieXuegong ShePublished in: Organic letters (2022)
The skeleton of lucidumone was constructed through oxidative dearomatization/intramolecular Diels-Alder reaction, Cu-mediated remote C-H hydroxylation, allyl oxidation, acid-promoted dynamic kinetic resolution cyclization, and benzylic oxidation.