Covalently Bonded Pillared Layered Bromoplumbate with High Thermal Stability: High Capacitance Gain after Photoinduced Electron Transfer.

Improving the stability and photoelectric properties are current aims in the field of inorganic-organic hybrid lead halides. In this work, a new covalently bonded pillared layered bromoplumbate, [Pb3Br6(CV)]n, was prepared using a photoactive zwitterion viologen, N,N'-4,4'-bipyridiniodipropionate (CV), as a ligand. It has a high thermal stability in air and shows a remarkable increase of capacitance after photoinduced electron transfer (PIET). The observed dielectric switch ratio of ∼689% at 3 kHz exceeded all reported values at room temperature for switchable dielectric materials. The capacitance gain was derived from the redistribution of electrons after PIET from the lead-halide layer to organic π-aggregates, so that the activation energy of hopping polarizability was significantly reduced.