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Low-Temperature Chiral Crystal Structure and Superconductivity in (Pt 0.2 Ir 0.8 ) 3 Zr 5 .

Yuto WatanabeHiroto ArimaAichi YamashitaAkira MiuraChikako MoriyoshiYosuke GotoChul-Ho LeeRyuji HigashinakaHidetomo UsuiShogo KawaguchiKazuhisa HoshiYoshikazu Mizuguchi
Published in: Journal of the American Chemical Society (2023)
We report the observation of superconductivity in (Pt 0.2 Ir 0.8 ) 3 Zr 5 with a chiral space group ( P 6 1 22) at low temperatures. The bulk nature of the superconductivity at a transition temperature of 2.2 K was confirmed using specific heat measurements. We revealed that (Pt 0.2 Ir 0.8 ) 3 Zr 5 obeys the weak-coupling Bardeen-Cooper-Schrieffer model, and the dominant mechanism in the upper critical field is the orbital pair-breaking limit rather than the Pauli-Clogston limit. This indicates that the antisymmetric spin-orbit coupling caused by the chiral crystal structure does not significantly affect the superconductivity of (Pt 0.2 Ir 0.8 ) 3 Zr 5 .
Keyphrases
  • crystal structure
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  • ionic liquid
  • mass spectrometry
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