Multiwall Carbon Nanotubes/Spherical Glassy Carbon as Environmentally Friendly Adsorption Materials Utilized in Adsorptive Stripping Voltammetry for the Determination of Trace Amounts of Ga(III).

This work presents a proposal for an adsorptive stripping voltammetric (AdSV) method for gallium(III) determination at an eco-friendly multiwall carbon nanotube/spherical glassy carbon (MWCNT/SGC) electrode modified with a lead film. The operational factors influencing the sensitivity of the AdSV procedure were thoroughly investigated, and their most favorable values were chosen (0.1 mol L -1 acetate buffer solution pH = 5.6; 7 × 10 -5 mol L -1 Pb(II); 2 × 10 -4 mol L -1 cupferron; potential/time of lead film formation: -1.9 V/30 s; potential/time of Ga(III)-cupferron adsorption: -0.75 V/30 s). The newly developed MWCNT/SGCE has proven to be a competitive substrate to the glassy carbon electrode to create a lead film electrode, since it allows the determination of gallium in a wider range of concentrations from 3 × 10 -9 to 4 × 10 -7 mol L -1 with a lower limit of detection equal to 9.5 × 10 -10 mol L -1 . The elaborated procedure has been shown to be highly selective and insensitive to the presence of an even 100-fold excess of most of the ions commonly found in environmental waters. The MWCNT/SGC sensor, which can maintain >95% of its original response after 70 days of use, has been successfully applied for the detection of gallium in water samples with the relative standard deviation (RSD) ranging from 4.5% to 6.2% ( n = 3) and recoveries in the range from 95.3% to 104.9%.