Etched ZIF-8 as a Filler in Mixed-Matrix Membranes for Enhanced CO2 /N2 Separation.

Zeolite ZIF-8 has been etched with acid to form microporous ZIF-8-E crystals. These were then introduced into a polyethersulfone (PES) membrane matrix to enhance its CO2 /N2 separation performance. Open through pores of size about 100 nm formed in the ZIF-8 crystals allow the ingrowth of polyethersulfone chains, ensuring a reduction in the number of nonselective voids, thereby achieving better interaction between ZIF-8-E and PES. As a result, the CO2 /N2 separation performance of the ZIF-8-E/PES membrane increased significantly, showing a CO2 permeability of 15.7 Barrer and a CO2 /N2 ideal selectivity of 6.5.