Ni-Cu Hydrotalcite-Derived Mixed Oxides as Highly Selective and Stable Catalysts for the Synthesis of β-Branched Bioalcohols by the Guerbet Reaction.

A series of Ni-Cu hydrotalcite-derived mixed oxides have been synthesized and evaluated as heterogeneous catalysts for the dimerization of linear aliphatic alcohols to afford β-branched Guerbet alcohols. The use of the hydrotalcite-structured catalyst precursor highly favors the catalyst stability. This Cu/Ni catalyst has an enhanced reducibility of Ni2+ species under reaction conditions, favoring the hydrogen transfer and hydrogenation capacity of the catalyst system. Catalytic results are reported for C8 , mixed C8 /C10 , and C18 alcohol feeds, with full conversions and Guerbet product purities of 72.5-96 %.