Stereoselective synthesis and properties of glycoazobenzene macrocycles through intramolecular glycosylation.
Chaoqi LinJinbiao JiaoStéphane MaisonneuveJulien MallétroitJuan XiePublished in: Chemical communications (Cambridge, England) (2020)
An intramolecular glycosylation strategy was used to synthesize a series of new glycoazobenzene macrocycles with high α-selectivity and interesting chiroptical properties. The photoisomerization of an azobenzene template influences mainly the efficiency of the glycosylation.