Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping.
P TomkinsA MansouriVitaly L SuskevichLars I van der WalSelmi Erim BozbağFrank KrumeichMarco RanocchiariJeroen Anton van BokhovenPublished in: Chemical science (2018)
PtCu- and PdCu-mordenite allow for isothermal reaction at 200 °C for the stepwise methane to methanol conversion with comparably high yields. In contrast to traditional Cu-zeolites, these materials are more reactive under isothermal conditions than after high temperature activation.