Detection of SO 2 F 2 Using a Photoacoustic Two-Chamber Approach.

The wide use of sulfuryl difluoride (SO 2 F 2 ) for termite control in buildings, warehouses and shipping containers requires the implementation of suitable sensors for reliable detection. SO 2 F 2 is highly toxic to humans and the environment, and moreover, it is a potent greenhouse gas. We developed two photoacoustic two-chamber sensors with the aim to detect two different concentration ranges, 0-1 vol.-% SO 2 F 2 and 0-100 ppm SO 2 F 2 , so that different applications can be targeted: the sensor for high concentrations for the effective treatment of buildings, containers, etc., and the sensor for low concentrations as personal safety device. Photoacoustic detectors were designed, fabricated, and then filled with either pure SO 2 F 2 or pure substituent gas, the refrigerant R227ea, to detect SO 2 F 2 . Absorption cells with optical path lengths of 50 mm and 1.6 m were built for both concentration ranges. The sensitivity to SO 2 F 2 as well as cross-sensitivities to CO 2 and H 2 O were measured. The results show that concentrations below 1 ppm SO 2 F 2 can be reliably detected, and possible cross-sensitivities can be effectively compensated.