Ultrasound-Induced Mechanoluminescence and Optical Thermometry Toward Stimulus-Responsive Materials with Simultaneous Trigger Response and Read-Out Functions.
Yicong DingByoungjin SoJiangkun CaoLothar WondraczekPublished in: Advanced science (Weinheim, Baden-Wurttemberg, Germany) (2022)
Ultrasound-induced mechanoluminescence (USML) of Erbium-doped CaZnOS is reported. Using the fluorescence intensity ratio of the 2 H 11/2 , 4 S 3/2 → 4 I 15/2 transitions of Er 3+ allows for simultaneous temperature mapping at an absolute sensitivity of 0.003 K -1 in the physiological regime. The combination of USML, local heating, and remote read-out enables a feedback and response loop for highly controlled stimulation. It is found that ML is a result of direct energy transfer from the host material to Er 3+ , giving room for adapted spectral characteristics through bandgap modulation. ML saturation at high acoustic power enables independent control of local light emission and ultrasonic heating. Such USML materials may have profound implications for optogenetics, photodynamic therapy and other areas requiring local illumination, heating, and thermometry simultaneously.
Keyphrases
- energy transfer
- photodynamic therapy
- quantum dots
- single molecule
- high glucose
- magnetic resonance imaging
- diabetic rats
- high resolution
- drug induced
- optical coherence tomography
- estrogen receptor
- computed tomography
- breast cancer cells
- oxidative stress
- transcription factor
- intellectual disability
- mass spectrometry
- magnetic resonance
- autism spectrum disorder
- high speed
- cancer therapy
- dual energy