Electrocatalytic Synthesis of Hydrogen Peroxide over Au/TiO2 and Electrochemical Trace of OOH* Intermediate.

In this work, a series of gold-supported titanium oxide composites have been prepared and high selectivity (over 90%) of hydrogen peroxide is achieved. For the first time, electrochemical impedance spectroscopy and electron spin resonance analysis demonstrate that high charge transfer impedance of the catalyst can suppress the decomposition of OOH* intermediates thus promoting the two-electron process of the oxygen reduction reaction.