Selective hydroboration of equilibrating allylic azides.
Ru-Zhang LiuYuanyuan ZhangJun XuPublished in: Chemical communications (Cambridge, England) (2021)
The iridium(I)-catalyzed hydroboration of equilibrating allylic azides is reported to provide only the anti-Markovnikov product of alk-1-ene isomers in good yields and with good functional group tolerance.