Login / Signup

Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic E- Z Isomerization of Olefins.

Mohitosh BhadraSharath KandambethManoj K SahooMatthew AddicoatEkambaram BalaramanRahul Banerjee
Published in: Journal of the American Chemical Society (2019)
Visible light-mediated photocatalytic organic transformation has drawn significant attention as an alternative process for replacing thermal reactions. Although precious metal/organic dyes based homogeneous photocatalysts have been developed, their toxic and nonreusable nature makes them inappropriate for large-scale production. Therefore, we have synthesized a triazine and a keto functionalized nonmetal based covalent organic framework (TpTt) for heterogeneous photocatalysis. As the catalyst shows significant absorption of visible light, it has been applied for the photocatalytic uphill conversion of trans-stilbene to cis-stilbene in the presence of blue light-emitting diodes with broad substrate scope via an energy transfer process.
Keyphrases
  • visible light
  • quantum dots
  • energy transfer
  • water soluble
  • working memory
  • molecularly imprinted
  • solid phase extraction
  • mass spectrometry
  • reduced graphene oxide
  • tissue engineering
  • tandem mass spectrometry