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Semi-Solid Supramolecular Ionic Network Electrolytes Formed by Zwitterionic Liquids and Polyoxometalate Nanoclusters for High Proton Conduction.

Xiang LiShengchao ChaiLiang ZhaiHaikun GuoHaibo HeHaibin LiLixin WuHao-Long Li
Published in: Macromolecular rapid communications (2023)
Flexible electrolytes with solid self-supporting properties are highly desired in the fields of energy and electronics. However, traditional flexible electrolytes prepared by doping ionic liquids or salt solutions into a polymer matrix pose a risk of liquid component leakage during device operation. In this work, we report the development of supramolecular ionic network electrolytes using polyoxometalate nanoclusters as supramolecular crosslinkers to solidify bola-type zwitterionic liquids. The resulting self-supporting electrolytes possess semi-solid features and show a high proton conductivity of 8.2×10 -4 S cm -1 at low humidity (RH = 30%). Additionally, the electrolytes exhibit a typical plateau region in rheological tests, indicating that their dynamic network structures can contribute mechanical behavior similar to the entangled networks in covalent polymer materials. This work introduces a new paradigm for designing flexible solid electrolytes and expands the concept of reticular chemistry to noncrystalline systems. This article is protected by copyright. All rights reserved.
Keyphrases
  • ionic liquid
  • solid state
  • room temperature
  • energy transfer
  • metal organic framework