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A magnetically focused molecular beam source for deposition of spin-polarised molecular surface layers.

Constantin R KrügerE Lisitsin-BaranovskyO OferP-A TurgeonJ VermetteP AyotteG Alexandrowicz
Published in: The Journal of chemical physics (2018)
Separating molecular spin isomers is a challenging task, with potential applications in various fields ranging from astrochemistry to magnetic resonance imaging. A new promising method for spin-isomer separation is magnetic focusing, a method which was shown to be capable of producing a molecular beam of ortho-water. Here, we present results from a modified magnetic focusing apparatus and show that it can be used to separate the spin isomers of acetylene and methane. From the measured focused profiles of the molecular beams and a numerical simulation analysis, we provide estimations for the spin purity and the significantly improved molecular flux obtained with the new setup. Finally, we discuss the spin-relaxation conditions which will be needed to apply this new source for measuring nuclear magnetic resonance signals of a single surface layer.
Keyphrases
  • single molecule
  • room temperature
  • magnetic resonance imaging
  • density functional theory
  • magnetic resonance
  • computed tomography
  • transition metal
  • molecularly imprinted
  • contrast enhanced
  • human health