Emerging Trends in Porogens toward Material Fabrication: Recent Progresses and Challenges.

Fabrication of tailor-made materials requires meticulous planning, use of technical equipments, major components and suitable additives that influence the end application. Most of the processes of separation/transport/adsorption have environmental applications that demands a material to be with measurable porous nature, stability (mechanical, thermal) and morphology. Researchers say that a vital role is played by porogens in this regard. Porogens (i.e., synthetic, natural, mixed) and their qualitative and quantitative influence on the substrate material (polymers (bio, synthetic), ceramic, metals, etc.) and their fabrication processes are summarized. In most cases, porogens critically influence the morphology, performance, surface and cross-section, which are directly linked to material efficiency, stability, reusability potential and its applications. However, currently there are no review articles exclusively focused on the porogen pores' role in material fabrication in general. Accordingly, this article comprises a review of the literature on various types of porogens, their efficiency in different host materials (organic, inorganic, etc.), pore size distribution (macro, micro and nano), their advantages and limitations, to a certain extent, and their critical applications. These include separation, transport of pollutants, stability improvement and much more. The progress made and the remaining challenges in porogens' role in the material fabrication process need to be summarized for researcher's attention.