Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand.

S SchnitzlerP CuiT P SpaniolJun Okuda

Published in: Dalton transactions (Cambridge, England : 2003) (2018)

Molecular magnesium hydride with a terminal metal-hydrogen bond [Mg(iPr2TACN·AliBu3)H]2 supported by a monoanionic TACN-type ligand (TACN = 1,4-di-isopropyl-1,4,7-triazacyclononane) rearranges to form the dinuclear magnesium hydride [Mg(iPr2TACN·AlHiBu2)(μ-H)]2, exhibiting a rare MgH-Al interaction.

Keyphrases

single molecule
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visible light